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Ethyl 4,4,4-trifluorocrotonate, 1 X 5 g (269697-5G)

SKU:
269697-5G
$88.96
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The Michael reaction between ethyl 4,4,4-trifluorocrotonate and a Ni(II) complex of the Schiff base of glycine with (S)-o-[N-(N-benzylprolyl)amino]benzophenone was studied. Ethyl 4,4,4-trifluorocrotonate was used in the synthesis of (2S,3S)-3-methyl- and (2S,3S)-3-trifluoromethylpyroglutamic acid. It undergoes diastereoselective Michael additio…

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formliquid
InChI1S/C6H7F3O2/c1-2-11-5(10)3-4-6(7,8)9/h3-4H,2H2,1H3/b4-3+
density1.125 g/mL at 25 °C (lit.)
InChI keyZKRJCMKLCDWROR-ONEGZZNKSA-N
functional groupfluoro
assay98%
CAS_NO406-10-0
bp114-115 °C (lit.)
functional groupester
Quality Level100
refractive indexn20/D 1.3601 (lit.)
SMILES stringCCOC(=O)\C=C\C(F)(F)F
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