Ir[dFFppy]₂-(4,4′-dCF₃bpy)PF₆, 100 mg (902217-100MG)

Under a dual catalytic copper/photoredox manifold, the Mes-Umemoto reagent has been demonstrated to be an excellent photocatalyst for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF₃ and aryl-CF₃ in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroarenes under mild conditions. For trifluoromethylation reactions, use with dMesSCF₃ (901466) and supersilanol (902489). Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080) A radical approach to the copper oxidative addition problem:Trifluoromethylation of bromoarenes Catalytic alkylation of remote C-H bonds enabled by proton-coupled electron transfer

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