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(R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine, 1 X 50 g (88719-50G)

SKU:
88719-50G
$12,037.06
Net 30 Terms Available

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(R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine (PPF-ᵗBu) is a chiral ferrocenyl diphosphine ligand. It may be used as a ligand in the palladium-catalyzed alkoxycarbonylation of 6-bromo-1,4-benzodioxane with sodium tert-butoxide to form the corresponding tert-butyl ester.
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functional groupphosphine
assay≥97%
formcrystals
optical purityee: ≥99%
CAS_NO155830-69-6
InChI1S/C27H35P2.C5H5.Fe/c1-21(29(26(2,3)4)27(5,6)7)24-19-14-20-25(24)28(22-15-10-8-11-16-22)23-17-12-9-13-18-23;1-2-4-5-3-1;/h8-21H,1-7H3;1-5H;/t21-;;/m1../s1
Quality Level100
InChI keySTAGMXYQPGLLTD-GHVWMZMZSA-N
SMILES string[Fe].[CH]1[CH][CH][CH][CH]1.C[C@H]([C]2[CH][CH][CH][C]2P(c3ccccc3)c4ccccc4)P(C(C)(C)C)C(C)(C)C
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