Rh₂(R-PTAD)4 , 250 mg (905356-250MG)

MilliporeSigma® (Sigma-Aldrich)

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905356-250MG

$528.65

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This chiral Rh(II) dimer was developed in the Davies lab to perform asymmetric carbene and nitrene reactions (C-H insertion, cyclopropanation, aziridination, C-H amination) with high regio- and stereo-control. Dirhodium Tetracarboxylate Derived from Adamantylglycine as a Chiral Catalyst for Carbenoid Reactions Asymmetric Synthesis of Tropane…

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SDS

CAS_NO	909393-65-3
SMILES string	[Rh]([Rh](OC(=O)[C@H](N%19C(=O)c%20c(cccc%20)C%19=O)C%17%16C[C@@H]%18C[C@@H](C[C@@H](C%18)C%17)C%16)OC(=O)[C@H](N%14C(=O)c%15c(cccc%15)C%14=O)C%12%11C[C@@H]%13C[C@@H](C[C@@H](C%13)C%12)C%11)(OC(=O)[C@H](N9C(=O)c%10c(cccc%10)C9=O)C76C[C@@H]8C[C@@H](C[C@@H]
form	powder or crystals
InChI	1S/4C20H21NO4.2Rh/c422-17-14-3-1-2-4-15(14)18(23)21(17)16(19(24)25)20-8-11-5-12(9-20)7-13(6-11)10-20;;/h41-4,11-13,16H,5-10H2,(H,24,25);;/q;;;;2+2/p-4/t411-,12+,13-,16-,20?;;/m0000../s1
InChI key	SGEDWOHAUXKUGM-VMLWFVNWSA-J
mp	>300 °C

Rh₂(R-PTAD)4 , 250 mg (905356-250MG)

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Rh₂(R-PTAD)4 , 250 mg (905356-250MG)

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