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(S)-T-BINAP, 1 X 500 mg (693030-500MG)

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693030-500MG
$85.16
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(S)-T-BINAP reacts with silver nitrate to form (S)-Tol-BINAP·AgNO₃, which can catalyze the enantioselective allylation reaction of aldehydes to form enantiopure secondary alcohols. It may be used as a chiral ligand in the palladium catalyzed asymmetric double carbohydroamination of iodoarenes to form α-aminoamides. It can also catalyze the asym…

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CAS_NO100165-88-6
InChI1S/C48H40P2/c1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-42/h5-32H,1-4H3
Quality Level100
optical activity[α]20/D -156°, c = 0.5 in benzene
InChI keyIOPQYDKQISFMJI-UHFFFAOYSA-N
SMILES stringP(c8ccc(cc8)C)(c7ccc(cc7)C)c1c(c6c(cc1)cccc6)c2c3c(ccc2P(c5ccc(cc5)C)c4ccc(cc4)C)cccc3
formsolid
functional groupphosphine
mp250-255 °C
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